The Cu-4 derivatives of [EtSiO2]Na have been synthesised and their cyclic voltammetry, spectroscopic behaviour and X-ray structure determination described. The changes in the alkali cation, Na+ in place of K+, might have a tuning effect in the organisation on the siloxanolate clusters resulting in a macrocyclic ([EtSiO2](12)) ligand instead of two cyclic ([EtSiO2](6)) ligands.
Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect? / C., Zucchi; M., Mattioli; G., Gavioli; M., Moret; A., Sironi; R., Ugo; M., Pizzotti; Oi, Shchegolikhina; Palyi, Gyula. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - (2000), pp. 1327-1331. [10.1002/(SICI)1099-0682(200006)2000:6<1327::AID-EJIC1327>3.3.CO;2-M]
Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect?
PALYI, Gyula
2000
Abstract
The Cu-4 derivatives of [EtSiO2]Na have been synthesised and their cyclic voltammetry, spectroscopic behaviour and X-ray structure determination described. The changes in the alkali cation, Na+ in place of K+, might have a tuning effect in the organisation on the siloxanolate clusters resulting in a macrocyclic ([EtSiO2](12)) ligand instead of two cyclic ([EtSiO2](6)) ligands.
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
