The Cu-4 derivatives of [EtSiO2]Na have been synthesised and their cyclic voltammetry, spectroscopic behaviour and X-ray structure determination described. The changes in the alkali cation, Na+ in place of K+, might have a tuning effect in the organisation on the siloxanolate clusters resulting in a macrocyclic ([EtSiO2](12)) ligand instead of two cyclic ([EtSiO2](6)) ligands.
Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect? / C., Z., M., M., G., G., M., M., A., S., R., U., M., P., Oi, S., Palyi, G.. - In: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. - ISSN 1434-1948. - (2000), pp. 1327-1331. [10.1002/(SICI)1099-0682(200006)2000:6<1327::AID-EJIC1327>3.3.CO;2-M]
Chemoselectivity in cyclosiloxanolate cluster formation: An alkali cation effect?
PALYI, Gyula
2000
Abstract
The Cu-4 derivatives of [EtSiO2]Na have been synthesised and their cyclic voltammetry, spectroscopic behaviour and X-ray structure determination described. The changes in the alkali cation, Na+ in place of K+, might have a tuning effect in the organisation on the siloxanolate clusters resulting in a macrocyclic ([EtSiO2](12)) ligand instead of two cyclic ([EtSiO2](6)) ligands.
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