A novel application of (PhO)(3)P-Cl-2 chemistry to the synthesis of 2-substituted and 2,3-disubstituted pyrroles from N-allylamides is illustrated. A mild procedure is Used to generate the imino chloride intermediates, which are subsequently cyclized to pyrroles. The products are smoothly obtained in moderate to good overall yields.

The triphenyl phosphite-chlorine reagent in the synthesis of pyrroles from N-allylamides / Spaggiari, Alberto; Vaccari, Daniele; Davoli, Paolo; Prati, Fabio. - In: SYNTHESIS. - ISSN 0039-7881. - STAMPA. - 37:6(2006), pp. 995-998. [10.1055/s-2006-926365]

The triphenyl phosphite-chlorine reagent in the synthesis of pyrroles from N-allylamides

SPAGGIARI, Alberto;VACCARI, Daniele;DAVOLI, Paolo;PRATI, Fabio
2006

Abstract

A novel application of (PhO)(3)P-Cl-2 chemistry to the synthesis of 2-substituted and 2,3-disubstituted pyrroles from N-allylamides is illustrated. A mild procedure is Used to generate the imino chloride intermediates, which are subsequently cyclized to pyrroles. The products are smoothly obtained in moderate to good overall yields.
2006
37
6
995
998
The triphenyl phosphite-chlorine reagent in the synthesis of pyrroles from N-allylamides / Spaggiari, Alberto; Vaccari, Daniele; Davoli, Paolo; Prati, Fabio. - In: SYNTHESIS. - ISSN 0039-7881. - STAMPA. - 37:6(2006), pp. 995-998. [10.1055/s-2006-926365]
Spaggiari, Alberto; Vaccari, Daniele; Davoli, Paolo; Prati, Fabio
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/307413
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