We report the preparation and characterization of the complexes of rhodium(III), iridium(III), palladium(II) and platinum(II) with the following ligands: Pzdtc, N-MePzdtc, N-PhPzdtc, Pipdtc, 4- PhPipdtc, Morphdtc, Timdtc, and with their methyl esters.The dithio ligands act as bidentate S,S′-donors in all the new derivatives. From the electronic absorption spectra the values of the ligand field parameters were determined. The nephelauxetic parameters are indicative of a strong covalency in the metal-ligand bond. All the compounds reported here are diamagnetic.

Dithiocarbamate complexes of rhodium (III), iridium (III), palladium (II) and platinum (II) / A. C., Fabretti; C., Preti; Tassi, Lorenzo; G., Tosi; Zannini, Paolo. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 137:(1987), pp. 73-74.

Dithiocarbamate complexes of rhodium (III), iridium (III), palladium (II) and platinum (II)

TASSI, Lorenzo;ZANNINI, Paolo
1987

Abstract

We report the preparation and characterization of the complexes of rhodium(III), iridium(III), palladium(II) and platinum(II) with the following ligands: Pzdtc, N-MePzdtc, N-PhPzdtc, Pipdtc, 4- PhPipdtc, Morphdtc, Timdtc, and with their methyl esters.The dithio ligands act as bidentate S,S′-donors in all the new derivatives. From the electronic absorption spectra the values of the ligand field parameters were determined. The nephelauxetic parameters are indicative of a strong covalency in the metal-ligand bond. All the compounds reported here are diamagnetic.
1987
137
73
74
Dithiocarbamate complexes of rhodium (III), iridium (III), palladium (II) and platinum (II) / A. C., Fabretti; C., Preti; Tassi, Lorenzo; G., Tosi; Zannini, Paolo. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 137:(1987), pp. 73-74.
A. C., Fabretti; C., Preti; Tassi, Lorenzo; G., Tosi; Zannini, Paolo
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/307392
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