Functionalized beta-lactams are synthesized by carbonylative ring expansion of silylated hydroxymethyl aziridines catalyzed by dicobalt octacarbonyl, a process that proceeds with inversion of configuration. Ring opening and elimination occurs on attempted carbonylation of aziridine carboxylates.

Carbonylation of silylated hydroxymethyl aziridines to beta-lactams / Davoli, Paolo; Moretti, Irene; Prati, Fabio; H., Alper. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 64:(1999), pp. 518-521.

Carbonylation of silylated hydroxymethyl aziridines to beta-lactams

DAVOLI, Paolo;MORETTI, Irene;PRATI, Fabio;
1999

Abstract

Functionalized beta-lactams are synthesized by carbonylative ring expansion of silylated hydroxymethyl aziridines catalyzed by dicobalt octacarbonyl, a process that proceeds with inversion of configuration. Ring opening and elimination occurs on attempted carbonylation of aziridine carboxylates.
64
518
521
Carbonylation of silylated hydroxymethyl aziridines to beta-lactams / Davoli, Paolo; Moretti, Irene; Prati, Fabio; H., Alper. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 64:(1999), pp. 518-521.
Davoli, Paolo; Moretti, Irene; Prati, Fabio; H., Alper
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/307137
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