Functionalized beta-lactams are synthesized by carbonylative ring expansion of silylated hydroxymethyl aziridines catalyzed by dicobalt octacarbonyl, a process that proceeds with inversion of configuration. Ring opening and elimination occurs on attempted carbonylation of aziridine carboxylates.

Carbonylation of silylated hydroxymethyl aziridines to beta-lactams / Davoli, Paolo; Moretti, Irene; Prati, Fabio; H., Alper. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 64:(1999), pp. 518-521.

Carbonylation of silylated hydroxymethyl aziridines to beta-lactams

DAVOLI, Paolo;MORETTI, Irene;PRATI, Fabio;
1999

Abstract

Functionalized beta-lactams are synthesized by carbonylative ring expansion of silylated hydroxymethyl aziridines catalyzed by dicobalt octacarbonyl, a process that proceeds with inversion of configuration. Ring opening and elimination occurs on attempted carbonylation of aziridine carboxylates.
1999
64
518
521
Carbonylation of silylated hydroxymethyl aziridines to beta-lactams / Davoli, Paolo; Moretti, Irene; Prati, Fabio; H., Alper. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 64:(1999), pp. 518-521.
Davoli, Paolo; Moretti, Irene; Prati, Fabio; H., Alper
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/307137
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 91
  • ???jsp.display-item.citation.isi??? 77
social impact