The crystal and molecular structure of Disodium bis(N-toluensulfonylglycinateN,O) palladate(II) compexes is determined. The structure consists of monomeric bis(N-toluensulfonylglycinateN,O) palladate(II) dianion and sodium cations. The coordination geometry around Pd(II) ions is planar and the aminoacidate moiety acts as bidentate chelate ligand by means of deprotonated sulfonyl nitrogen and one carboxylate oxygen.
Deprotonated amide nitrogen coordinating to the palladium(II) ion.Crystal and molecular structure of disodium bis)N-tosylglycinato-N,O)palladate(II) / Menabue, Ledi; Saladini, Monica; Sola, Marco. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 29:(1990), pp. 1293-1295.
Deprotonated amide nitrogen coordinating to the palladium(II) ion.Crystal and molecular structure of disodium bis)N-tosylglycinato-N,O)palladate(II)
MENABUE, Ledi;SALADINI, Monica;SOLA, Marco
1990
Abstract
The crystal and molecular structure of Disodium bis(N-toluensulfonylglycinateN,O) palladate(II) compexes is determined. The structure consists of monomeric bis(N-toluensulfonylglycinateN,O) palladate(II) dianion and sodium cations. The coordination geometry around Pd(II) ions is planar and the aminoacidate moiety acts as bidentate chelate ligand by means of deprotonated sulfonyl nitrogen and one carboxylate oxygen.
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