The preparation of a new thiophenic dimer partially derivatized with a bromohexylic chain is described. its polymerization under mild oxidative conditions leads to a polythiophene with a degree of functionalization Of 50% and highly soluble in organic solvents. The product has been fully characterized by FT-IR, H-1 and C-13 NMR using one and two-dimensional techniques as well as by SEC and thermal analysis. Solvatochromic effects of the new polymer have been investigated in different mixtures, underlining its self-assembling capability even in solvated states.
Novel Thiophenic Copolymer as a Multi-Purpose Macromolecular Intermediate / L., Paganin; P., Costa Bizzarri; M., Lanzi; G., Cesari; F., Bertinelli; Cagnoli, Rita; Mucci, Adele. - In: MACROMOLECULAR SYMPOSIA. - ISSN 1022-1360. - STAMPA. - 234:1(2006), pp. 76-86. [10.1002/masy.200650211]
Novel Thiophenic Copolymer as a Multi-Purpose Macromolecular Intermediate
CAGNOLI, Rita;MUCCI, Adele
2006-01-01
Abstract
The preparation of a new thiophenic dimer partially derivatized with a bromohexylic chain is described. its polymerization under mild oxidative conditions leads to a polythiophene with a degree of functionalization Of 50% and highly soluble in organic solvents. The product has been fully characterized by FT-IR, H-1 and C-13 NMR using one and two-dimensional techniques as well as by SEC and thermal analysis. Solvatochromic effects of the new polymer have been investigated in different mixtures, underlining its self-assembling capability even in solvated states.
| File | Dimensione | Formato | |
|---|---|---|---|
|
macromol. symp. 2006.pdf
Accesso riservato
Tipologia:
Versione pubblicata dall'editore
Dimensione
417.77 kB
Formato
Adobe PDF
|
417.77 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
