(S)-(-)-N-acetyl-2-methoxycarbonylaziridine 1 undergoes easy ring-opening by Bronsted acids or nucleophiles in the presence of a Lewis acid catalyst. The regioselectivity is not always exclusive, affording optically active alpha- and beta-aminoacids.
Regioselectivity of Ring-opening reactions of optically active N-Acetyl-2-Methoxycarbonyl aziridine / Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 6:(1995), pp. 2073-2080.
Regioselectivity of Ring-opening reactions of optically active N-Acetyl-2-Methoxycarbonyl aziridine
BUCCIARELLI, Maria;FORNI, Arrigo;MORETTI, Irene;PRATI, Fabio;TORRE, Giovanni
1995
Abstract
(S)-(-)-N-acetyl-2-methoxycarbonylaziridine 1 undergoes easy ring-opening by Bronsted acids or nucleophiles in the presence of a Lewis acid catalyst. The regioselectivity is not always exclusive, affording optically active alpha- and beta-aminoacids.
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