The paper investigated, by means of thermal analysis measurements. the validity of three different methods for the evaluation of the activation energy of crystallization for surface nucleated glasses belonging to the MgO-CaO-Al2O3-SiO2 system, separating anorthite and diopside crystals. The values obtained from Kissinger equation of the activation energy for crystallization are comparable with those obtained by other authors for similar glassy systems, 90 to 150 kcal/mol. The results of the kinetic analysis using single-crystallization-peak method should be corrected taking into account the dimensionality of crystal growth.
Kinetic study of surface nucleated MgO-CaO-Al2O3-SiO2 glasses / Barbieri, Luisa; Leonelli, Cristina; Manfredini, Tiziano; M., Paganelli; Pellacani, Gian Carlo. - In: JOURNAL OF THERMAL ANALYSIS. - ISSN 0368-4466. - STAMPA. - 38(12):(1992), pp. 2639-2647.
Kinetic study of surface nucleated MgO-CaO-Al2O3-SiO2 glasses
BARBIERI, Luisa;LEONELLI, Cristina;MANFREDINI, Tiziano;PELLACANI, Gian Carlo
1992
Abstract
The paper investigated, by means of thermal analysis measurements. the validity of three different methods for the evaluation of the activation energy of crystallization for surface nucleated glasses belonging to the MgO-CaO-Al2O3-SiO2 system, separating anorthite and diopside crystals. The values obtained from Kissinger equation of the activation energy for crystallization are comparable with those obtained by other authors for similar glassy systems, 90 to 150 kcal/mol. The results of the kinetic analysis using single-crystallization-peak method should be corrected taking into account the dimensionality of crystal growth.
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