A novel single-molecule magnet of the Mn-12 family, [Mn12O12(O2CC6H5)8(L)4(H2O)4].8CH2Cl2, has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2-), which leads to selective occupation of axial binding sites.
Site-specific Ligation of Anthracene-1,8-Dicarboxylates to an Mn12 Core: a Route to the Controlled Functionalisation of Single-Molecule Magnets / M., PACCHIONI; CORNIA, Andrea; FABRETTI COSTANTINO, Antonio; ZOBBI, Laura; D., BONACCHI; A., CANESCHI; G., CHASTANET; D., GATTESCHI; R., SESSOLI. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - (none):(2004), pp. 2604-2605.
Site-specific Ligation of Anthracene-1,8-Dicarboxylates to an Mn12 Core: a Route to the Controlled Functionalisation of Single-Molecule Magnets
CORNIA, Andrea;FABRETTI COSTANTINO, Antonio;ZOBBI, Laura;
2004
Abstract
A novel single-molecule magnet of the Mn-12 family, [Mn12O12(O2CC6H5)8(L)4(H2O)4].8CH2Cl2, has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2-), which leads to selective occupation of axial binding sites.
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