(R)-(+) and (S)-(-) ethyl 4,4,4-trifluoro-3-hydroxybutanoate are obtained both by enantioselective Baker's yeast reduction of ethyl 4,4,4-trifluoro-3-oxobutanoate in the presence of allyl bromide or allyl alcohol. The two additives act as inhibitors of Si or Re yeast-enzymes, respectively. (C) 1999 Elsevier Science Inc. All rights reserved.
(R)-(+) and (S)-(-) ethyl 4,4,4-trifluoro-3-hydroxy butanoate by enantioselective Baker's yeast reduction / Davoli, Paolo; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni. - In: ENZYME AND MICROBIAL TECHNOLOGY. - ISSN 0141-0229. - STAMPA. - 25:(1999), pp. 149-152.
(R)-(+) and (S)-(-) ethyl 4,4,4-trifluoro-3-hydroxy butanoate by enantioselective Baker's yeast reduction
DAVOLI, Paolo;FORNI, Arrigo;MORETTI, Irene;PRATI, Fabio;TORRE, Giovanni
1999
Abstract
(R)-(+) and (S)-(-) ethyl 4,4,4-trifluoro-3-hydroxybutanoate are obtained both by enantioselective Baker's yeast reduction of ethyl 4,4,4-trifluoro-3-oxobutanoate in the presence of allyl bromide or allyl alcohol. The two additives act as inhibitors of Si or Re yeast-enzymes, respectively. (C) 1999 Elsevier Science Inc. All rights reserved.
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