Hydroxylation and/or ketonization of alkanes (adamantane, cyclo-octene, hexane) is achieved by using iodosobenzene or aqueous mono-persulfate at room temperature in the presence of catalytic amounts of ruthenium(III)-diphosphino complexes dissolved in dichloromethane. On the basis of the kinetic behavior, different oxidizing metal species are proposed for the oxidations with mono-persulfate and with iodosobenzene.
Iodosobenzene and persulfate oxygenation of saturated hydrocarbons catalyzed by diphosphino complexes of ruthenium(III) / M., Bressan; Forti, Luca; A., Morvillo. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 211:(1993), pp. 217-220. [10.1016/S0020-1693(00)85605-4]
Iodosobenzene and persulfate oxygenation of saturated hydrocarbons catalyzed by diphosphino complexes of ruthenium(III)
FORTI, Luca;
1993
Abstract
Hydroxylation and/or ketonization of alkanes (adamantane, cyclo-octene, hexane) is achieved by using iodosobenzene or aqueous mono-persulfate at room temperature in the presence of catalytic amounts of ruthenium(III)-diphosphino complexes dissolved in dichloromethane. On the basis of the kinetic behavior, different oxidizing metal species are proposed for the oxidations with mono-persulfate and with iodosobenzene.
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