Electrodes covered by stable electron conducting polymer films which exhibit easy p- and relatively easy n-doping have been successfully prepared by electrochemical polymerisation of symmetrical 4,4'-bisbutylsulfanyl-2,2'-bithiophene. The whole of the cyclic voltammetric behaviour has been explained based on the concept of 'electrostatically stabilised polarons'.
P- and n-doping of electrochemically formed poly(4,4 '-bisbutylsulfanyl-2,2 '-bithiophene). A novel material with reduced bandgap / H., Ding; Pigani, Laura; Seeber, Renato; Zanardi, Chiara. - In: JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS. - ISSN 1480-2422. - STAMPA. - 3:4(2000), pp. 337-341.
P- and n-doping of electrochemically formed poly(4,4 '-bisbutylsulfanyl-2,2 '-bithiophene). A novel material with reduced bandgap
PIGANI, Laura;SEEBER, Renato;ZANARDI, Chiara
2000
Abstract
Electrodes covered by stable electron conducting polymer films which exhibit easy p- and relatively easy n-doping have been successfully prepared by electrochemical polymerisation of symmetrical 4,4'-bisbutylsulfanyl-2,2'-bithiophene. The whole of the cyclic voltammetric behaviour has been explained based on the concept of 'electrostatically stabilised polarons'.
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