The static dielectric constant (epsilon) has been measured at 2 MHz for N,N-dimethylformamide (1), 1,2-dimethoxyethane (2), and their nine binary mixtures covering the whole miscibility field (0 less-than-or-equal-to x1 less-than-or-equal-to 1) in the 40-80-degrees-C temperature range. The experimental epsilon values were fitted by empirical equations of the types epsilon = epsilon(T), epsilon = epsilon(x1), and epsilon = epsilon(T,x1). The mixing quantity deltaepsilon has been evaluated and fitted by a Redlich-Kister equation. The trend of deltaepsilon vs mole fraction curves shows negative deviations from ideality, and makes evident the presence of a stable dipolar interaction between unlike molecules.

N,N-dimethylformamide + 1,2-dimethoxyethane binary mixtures. The static dielectric constant from 40 to 80°C / L., Marcheselli; G., Pistoni; M., Tagliazucchi; Tassi, Lorenzo; G., Tosi. - In: JOURNAL OF CHEMICAL AND ENGINEERING DATA. - ISSN 0021-9568. - STAMPA. - 38(1993), pp. 204-206.

I documenti presenti in Iris Unimore sono rilasciati con licenza Creative Commons Attribuzione - Non commerciale - Non opere derivate 3.0 Italia, salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Powered by IRIS-about IRIS-Utilizzo dei cookie

 Copyright © 2020