The static dielectric constant (epsilon) has been measured at 2 MHz for N,N-dimethylformamide (1), 1,2-dimethoxyethane (2), and their nine binary mixtures covering the whole miscibility field (0 less-than-or-equal-to x1 less-than-or-equal-to 1) in the 40-80-degrees-C temperature range. The experimental epsilon values were fitted by empirical equations of the types epsilon = epsilon(T), epsilon = epsilon(x1), and epsilon = epsilon(T,x1). The mixing quantity deltaepsilon has been evaluated and fitted by a Redlich-Kister equation. The trend of deltaepsilon vs mole fraction curves shows negative deviations from ideality, and makes evident the presence of a stable dipolar interaction between unlike molecules.

N,N-dimethylformamide + 1,2-dimethoxyethane binary mixtures. The static dielectric constant from 40 to 80°C / L., Marcheselli; G., Pistoni; M., Tagliazucchi; Tassi, Lorenzo; G., Tosi. - In: JOURNAL OF CHEMICAL AND ENGINEERING DATA. - ISSN 0021-9568. - STAMPA. - 38:(1993), pp. 204-206.

N,N-dimethylformamide + 1,2-dimethoxyethane binary mixtures. The static dielectric constant from 40 to 80°C

TASSI, Lorenzo;
1993

Abstract

The static dielectric constant (epsilon) has been measured at 2 MHz for N,N-dimethylformamide (1), 1,2-dimethoxyethane (2), and their nine binary mixtures covering the whole miscibility field (0 less-than-or-equal-to x1 less-than-or-equal-to 1) in the 40-80-degrees-C temperature range. The experimental epsilon values were fitted by empirical equations of the types epsilon = epsilon(T), epsilon = epsilon(x1), and epsilon = epsilon(T,x1). The mixing quantity deltaepsilon has been evaluated and fitted by a Redlich-Kister equation. The trend of deltaepsilon vs mole fraction curves shows negative deviations from ideality, and makes evident the presence of a stable dipolar interaction between unlike molecules.
38
204
206
N,N-dimethylformamide + 1,2-dimethoxyethane binary mixtures. The static dielectric constant from 40 to 80°C / L., Marcheselli; G., Pistoni; M., Tagliazucchi; Tassi, Lorenzo; G., Tosi. - In: JOURNAL OF CHEMICAL AND ENGINEERING DATA. - ISSN 0021-9568. - STAMPA. - 38:(1993), pp. 204-206.
L., Marcheselli; G., Pistoni; M., Tagliazucchi; Tassi, Lorenzo; G., Tosi
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/305327
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