(eta(5)-C5H5)(2)M[Co(Co)(4)](2) (M = Ti, Zr) complexes were prepared by alkane elimination from the corresponding metallocene diorganyls and HCo(CO)(4) or by salt elimination from metallocene dihalides and Na[Co(CO)(4)]. (Ph(2)N)(2)Ti[Co(CO)(4)](2) was obtained from (Ph(2)N)(4)Ti and HCo(CO)(4).
Early/late bimetallic complexes: MCo2 (M = Ti, Zr) derivatives / T., Bartik; H., Windisch; A., Sorkau; Kh, Thiele; C., Kriebel; A., Herfurth; Cm, Tschoerner; C., Zucchi; Palyi, Gyula. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 227:(1994), pp. 201-205.
Early/late bimetallic complexes: MCo2 (M = Ti, Zr) derivatives
PALYI, Gyula
1994
Abstract
(eta(5)-C5H5)(2)M[Co(Co)(4)](2) (M = Ti, Zr) complexes were prepared by alkane elimination from the corresponding metallocene diorganyls and HCo(CO)(4) or by salt elimination from metallocene dihalides and Na[Co(CO)(4)]. (Ph(2)N)(2)Ti[Co(CO)(4)](2) was obtained from (Ph(2)N)(4)Ti and HCo(CO)(4).Pubblicazioni consigliate
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