The oligocyclosiloxane cluster ('sandwich') complex of Nd3+, Na-6{[(C6H5SiO2)(8)]Nd-2(4)(mu(4)-O)} has been prepared and characterized by analyses, infrared spectra, single crystal X-ray diffraction, magnetic susceptibility, conductivity and cyclic voltammetry. The mu(4)-O2- anion is in a square planar coordination environment. Electrochemical studies identify the cluster core as a moiety with a delocalized electron system.
Cyclosiloxane sandwich complexes of a lanthanide metal: Na-6{[(C6H5SiO2)(8)](2)Nd-4(mu(4)-O)} / Oi, S., Ya, P., Sv, L., Aa, Z., R., P., R., U., Gavioli, G., Battistuzzi, R., Borsari, M., T., R., Palyi, G., Zucchi, C.. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - STAMPA. - 514:(1996), pp. 29-35. [10.1016/0022-328X(95)06005-H]
Cyclosiloxane sandwich complexes of a lanthanide metal: Na-6{[(C6H5SiO2)(8)](2)Nd-4(mu(4)-O)}
GAVIOLI, Giovanna;BATTISTUZZI, Raffaele;BORSARI, Marco;PALYI, Gyula;ZUCCHI, Claudia
1996
Abstract
The oligocyclosiloxane cluster ('sandwich') complex of Nd3+, Na-6{[(C6H5SiO2)(8)]Nd-2(4)(mu(4)-O)} has been prepared and characterized by analyses, infrared spectra, single crystal X-ray diffraction, magnetic susceptibility, conductivity and cyclic voltammetry. The mu(4)-O2- anion is in a square planar coordination environment. Electrochemical studies identify the cluster core as a moiety with a delocalized electron system.
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