The Kharasch addition of methyl 2,2-dichlorocarboxylates or trichloro acetic acid derivatives to alkenes, affording the corresponding 1:1 adducts, is promoted by the iron filings/N,N-dimethylformamide system.
Halogen atom transfer radical addition of alpha-polychloroesters to olefins promoted by Fe-0 filings / Forti, Luca; Ghelfi, Franco; Libertini, Emanuela; Pagnoni, Ugo Maria; Soragni, Ercole. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 53:(1997), pp. 17761-17768. [10.1016/S0040-4020(97)10241-1]
Halogen atom transfer radical addition of alpha-polychloroesters to olefins promoted by Fe-0 filings
FORTI, Luca;GHELFI, Franco;LIBERTINI, Emanuela;PAGNONI, Ugo Maria;SORAGNI, Ercole
1997
Abstract
The Kharasch addition of methyl 2,2-dichlorocarboxylates or trichloro acetic acid derivatives to alkenes, affording the corresponding 1:1 adducts, is promoted by the iron filings/N,N-dimethylformamide system.
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