The high field EPR spectra of a Mn(III) compd. was obtained. The HF-EPR spectra of Mn(dbm)3, where Hdbm = 1,3-diphenyl-1,3-propanedione, can be used to provide information on g-factors and zero field splitting of Mn(III) complexes. The ligand field anal. can be used to obtain structure and electronic structure information of the complex.
Electronic Structure of Manganese(III) Compounds from High-frequency EPR Spectra / A. L., Barra; D., Gatteschi; R., Sessoli; G. L., Abbati; Cornia, Andrea; FABRETTI COSTANTINO, Antonio; M. G., Uytterhoeven. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - STAMPA. - 36:(1997), pp. 2329-2331.
Electronic Structure of Manganese(III) Compounds from High-frequency EPR Spectra
CORNIA, Andrea;FABRETTI COSTANTINO, Antonio;
1997
Abstract
The high field EPR spectra of a Mn(III) compd. was obtained. The HF-EPR spectra of Mn(dbm)3, where Hdbm = 1,3-diphenyl-1,3-propanedione, can be used to provide information on g-factors and zero field splitting of Mn(III) complexes. The ligand field anal. can be used to obtain structure and electronic structure information of the complex.
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