Crystals of the title compd., di-μ-croconato-bis{μ-[N,N'-bis(3-amino-2,2-dimethylpropyl)oxamidato(2-)-N,O':N',O]dicopper(II)} tetrahydrate, are triclinic, space group P-1, with a 9.496(1), b 10.6620(8), c 12.966(2) Å, α 71.481(8), β 75.780(10), γ 66.160(10)°; Z = 1, dc = 1.647, dm = 1.65(1); R = 0.032, Rw(F2) = 0.087 for 6246 reflections. The structure comprises two μ-oxamidato-dicopper(II) units bridged by croconate ligands to give a tetracopper(II) ring system with crystallog. -1 symmetry; all the Cu centers are five-coordinate.

A Tetracopper(II) Complex Containing Two μ-Oxamidato-dicopper(II) Units Linked by Croconate Anions / G. L., Abbati; Cornia, Andrea; FABRETTI COSTANTINO, Antonio. - In: ACTA CRYSTALLOGRAPHICA. SECTION C, CRYSTAL STRUCTURE COMMUNICATIONS. - ISSN 0108-2701. - STAMPA. - 55:(1999), pp. 2043-2045.

A Tetracopper(II) Complex Containing Two μ-Oxamidato-dicopper(II) Units Linked by Croconate Anions

CORNIA, Andrea;FABRETTI COSTANTINO, Antonio
1999

Abstract

Crystals of the title compd., di-μ-croconato-bis{μ-[N,N'-bis(3-amino-2,2-dimethylpropyl)oxamidato(2-)-N,O':N',O]dicopper(II)} tetrahydrate, are triclinic, space group P-1, with a 9.496(1), b 10.6620(8), c 12.966(2) Å, α 71.481(8), β 75.780(10), γ 66.160(10)°; Z = 1, dc = 1.647, dm = 1.65(1); R = 0.032, Rw(F2) = 0.087 for 6246 reflections. The structure comprises two μ-oxamidato-dicopper(II) units bridged by croconate ligands to give a tetracopper(II) ring system with crystallog. -1 symmetry; all the Cu centers are five-coordinate.
1999
55
2043
2045
A Tetracopper(II) Complex Containing Two μ-Oxamidato-dicopper(II) Units Linked by Croconate Anions / G. L., Abbati; Cornia, Andrea; FABRETTI COSTANTINO, Antonio. - In: ACTA CRYSTALLOGRAPHICA. SECTION C, CRYSTAL STRUCTURE COMMUNICATIONS. - ISSN 0108-2701. - STAMPA. - 55:(1999), pp. 2043-2045.
G. L., Abbati; Cornia, Andrea; FABRETTI COSTANTINO, Antonio
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/304611
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 16
  • ???jsp.display-item.citation.isi??? 16
social impact