Alcohols are oxidized to carbonylic compounds by aqueous persulfate in the presence of catalytic amounts (0.2%) of ruthenium trichloride and of a choice of ruthenium(II) complexes. Secondary alcohols are quantitatively converted to ketones, whereas primary alcohols can be converted to aldehydes with good selectivities. A kinetic investigation suggests a concerted mechanism for the bi-electronic oxygen transfer.
Ruthenium(II)-catalyzed oxidation of alcohols by persulfate / M., Bressan; Forti, Luca; Ghelfi, Franco; A., Morvillo. - In: JOURNAL OF MOLECULAR CATALYSIS. - ISSN 0304-5102. - STAMPA. - 79:(1993), pp. 85-93. [10.1016/0304-5102(93)85093-9]
Ruthenium(II)-catalyzed oxidation of alcohols by persulfate
FORTI, Luca;GHELFI, Franco;
1993
Abstract
Alcohols are oxidized to carbonylic compounds by aqueous persulfate in the presence of catalytic amounts (0.2%) of ruthenium trichloride and of a choice of ruthenium(II) complexes. Secondary alcohols are quantitatively converted to ketones, whereas primary alcohols can be converted to aldehydes with good selectivities. A kinetic investigation suggests a concerted mechanism for the bi-electronic oxygen transfer.
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