Methyl 2,2-dihalocarboxylates add easily to carbonyl compounds in fair to good yields through the intermediate formation of 2-haloester enolates; the reaction is promoted by zinc, following a ''Barbier'' type procedure.
Zinc promoted addition of methyl 2,2-dihalocarboxylates to carbonyl compounds / Benincasa, Marta; Forti, Luca; Ghelfi, Franco; Libertini, Emanuela; Pagnoni, Ugo Maria. - In: SYNTHETIC COMMUNICATIONS. - ISSN 0039-7911. - STAMPA. - 26:(1996), pp. 4113-4122. [10.1080/00397919608004648]
Zinc promoted addition of methyl 2,2-dihalocarboxylates to carbonyl compounds
BENINCASA, Marta;FORTI, Luca;GHELFI, Franco;LIBERTINI, Emanuela;PAGNONI, Ugo Maria
1996
Abstract
Methyl 2,2-dihalocarboxylates add easily to carbonyl compounds in fair to good yields through the intermediate formation of 2-haloester enolates; the reaction is promoted by zinc, following a ''Barbier'' type procedure.
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