Asymmetric reduction of oximes was performed by chromium (II) complexes of natural amino acids in aqueous phase or in H2O/DMF (1:1) solvent. Medium-to-quantitative chemoselectivity (54% to >95%) and low-to-medium enantioselectivity (5-50% ee) were found.
Enantioselective reduction of C=N double bond by chromium(II) complexes of natural amino acids / K., Micskei; O., Holczknecht; V., Marchis; A., Levai; T., Patonay; C., Zucchi; Palyi, Gyula. - In: CHIRALITY. - ISSN 0899-0042. - 17:9(2005), pp. 511-514. [10.1002/chir.20193]
Enantioselective reduction of C=N double bond by chromium(II) complexes of natural amino acids
PALYI, Gyula
2005
Abstract
Asymmetric reduction of oximes was performed by chromium (II) complexes of natural amino acids in aqueous phase or in H2O/DMF (1:1) solvent. Medium-to-quantitative chemoselectivity (54% to >95%) and low-to-medium enantioselectivity (5-50% ee) were found.
| File | Dimensione | Formato | |
|---|---|---|---|
|
chir.20193.pdf
Accesso riservato
Tipologia:
Versione pubblicata dall'editore
Dimensione
92.54 kB
Formato
Adobe PDF
|
92.54 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
