Asymmetric reduction of oximes was performed by chromium (II) complexes of natural amino acids in aqueous phase or in H2O/DMF (1:1) solvent. Medium-to-quantitative chemoselectivity (54% to >95%) and low-to-medium enantioselectivity (5-50% ee) were found.
Enantioselective reduction of C=N double bond by chromium(II) complexes of natural amino acids / K., Micskei; O., Holczknecht; V., Marchis; A., Levai; T., Patonay; C., Zucchi; Palyi, Gyula. - In: CHIRALITY. - ISSN 0899-0042. - 17:9(2005), pp. 511-514. [10.1002/chir.20193]
Enantioselective reduction of C=N double bond by chromium(II) complexes of natural amino acids
PALYI, Gyula
2005-01-01
Abstract
Asymmetric reduction of oximes was performed by chromium (II) complexes of natural amino acids in aqueous phase or in H2O/DMF (1:1) solvent. Medium-to-quantitative chemoselectivity (54% to >95%) and low-to-medium enantioselectivity (5-50% ee) were found.
| File | Dimensione | Formato | |
|---|---|---|---|
|
chir.20193.pdf
Accesso riservato
Tipologia:
Versione pubblicata dall'editore
Dimensione
92.54 kB
Formato
Adobe PDF
|
92.54 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
