Electrode deposits of a polythiophene with particularly interesting characteristics, i.e., poly[4,40-bis(butylsulphanyl)-2,20-bithiophene],have been generated in the presence of different supporting electrolytes. The formation of the coatings has been studied bycoupling conventional electrochemical techniques with quartz crystal microbalance measurements. The results of simultaneousvoltammetric or chronoamperometric and microgravimetric experiments allow us to show the influence exerted by the nature of thesupporting electrolyte on the polymerisation and concomitant charging–discharging processes of the conducting polymer.

Influence of the nature of the supporting electrolyte on the formation of poly[4,4'-bis(butylsulphanyl)-2,2'-bithiophene] films. A role for both counter-ion and co-ion in the polymer growth and p-doping processes / Pigani, Laura; Seeber, Renato; Terzi, Fabio; Zanardi, Chiara. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY. - ISSN 1572-6657. - STAMPA. - 562:(2004), pp. 231-239. [10.1016/j.jelechem.2003.09.006]

Influence of the nature of the supporting electrolyte on the formation of poly[4,4'-bis(butylsulphanyl)-2,2'-bithiophene] films. A role for both counter-ion and co-ion in the polymer growth and p-doping processes

PIGANI, Laura;SEEBER, Renato;TERZI, Fabio;ZANARDI, Chiara
2004

Abstract

Electrode deposits of a polythiophene with particularly interesting characteristics, i.e., poly[4,40-bis(butylsulphanyl)-2,20-bithiophene],have been generated in the presence of different supporting electrolytes. The formation of the coatings has been studied bycoupling conventional electrochemical techniques with quartz crystal microbalance measurements. The results of simultaneousvoltammetric or chronoamperometric and microgravimetric experiments allow us to show the influence exerted by the nature of thesupporting electrolyte on the polymerisation and concomitant charging–discharging processes of the conducting polymer.
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Influence of the nature of the supporting electrolyte on the formation of poly[4,4'-bis(butylsulphanyl)-2,2'-bithiophene] films. A role for both counter-ion and co-ion in the polymer growth and p-doping processes / Pigani, Laura; Seeber, Renato; Terzi, Fabio; Zanardi, Chiara. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY. - ISSN 1572-6657. - STAMPA. - 562:(2004), pp. 231-239. [10.1016/j.jelechem.2003.09.006]
Pigani, Laura; Seeber, Renato; Terzi, Fabio; Zanardi, Chiara
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11380/18310
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