Influence of the nature of the supporting electrolyte on the formation of poly[4,4'-bis(butylsulphanyl)-2,2'-bithiophene] films. A role for both counter-ion and co-ion in the polymer growth and p-doping processes

Pigani, Laura; Seeber, Renato; Terzi, Fabio; Zanardi, Chiara

doi:10.1016/j.jelechem.2003.09.006

Electrode deposits of a polythiophene with particularly interesting characteristics, i.e., poly[4,40-bis(butylsulphanyl)-2,20-bithiophene],have been generated in the presence of different supporting electrolytes. The formation of the coatings has been studied bycoupling conventional electrochemical techniques with quartz crystal microbalance measurements. The results of simultaneousvoltammetric or chronoamperometric and microgravimetric experiments allow us to show the influence exerted by the nature of thesupporting electrolyte on the polymerisation and concomitant charging–discharging processes of the conducting polymer.

Data di pubblicazione:	2004
Titolo:	Influence of the nature of the supporting electrolyte on the formation of poly[4,4'-bis(butylsulphanyl)-2,2'-bithiophene] films. A role for both counter-ion and co-ion in the polymer growth and p-doping processes
Autore/i:	Pigani, Laura; Seeber, Renato; Terzi, Fabio; Zanardi, Chiara
Autore/i UNIMORE:	PIGANI, Laura SEEBER, Renato TERZI, Fabio ZANARDI, Chiara
Digital Object Identifier (DOI):	http://dx.doi.org/10.1016/j.jelechem.2003.09.006
Rivista:	JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:	562
Pagina iniziale:	231
Pagina finale:	239
Codice identificativo ISI:	WOS:000188500500011
Codice identificativo Scopus:	2-s2.0-0347128432
Citazione:	Influence of the nature of the supporting electrolyte on the formation of poly[4,4'-bis(butylsulphanyl)-2,2'-bithiophene] films. A role for both counter-ion and co-ion in the polymer growth and p-doping processes / Pigani, Laura; Seeber, Renato; Terzi, Fabio; Zanardi, Chiara. - In: JOURNAL OF ELECTROANALYTICAL CHEMISTRY. - ISSN 1572-6657. - STAMPA. - 562(2004), pp. 231-239.
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http://hdl.handle.net/11380/18310

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