Recently, the formation of the ceramic-ionic liquid composite has attracted huge interest in the scientific community. In this work, we investigated the chemical reactions occurring between NASICON LAGP ceramic electrolyte and ionic liquid pyr13TFSI. This study allowed us to identify the cation exchange reaction pyr13-Li occurring on the LAGP surface, forming a LiTFSI salt that was detected by the nuclear magnetic resonance analysis. In addition, using 6Li foils, we succeeded in demonstrating that both LAGP and LiTFSI:pyr13TFSI participate in the diffusion of Li ions by the formation of an ionic bridge between two species.

Unveiling the Cation Exchange Reaction between the NASICON Li1.5Al0.5Ge1.5(PO4)3Solid Electrolyte and the pyr13TFSI Ionic Liquid / Paolella, A.; Bertoni, G.; Zhu, W.; Campanella, D.; La Monaca, A.; Girard, G.; Demers, H.; Gheorghe Nita, A. C.; Feng, Z.; Vijh, A.; Guerfi, A.; Trudeau, M.; Armand, M.; Krachkovskiy, S. A.. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 144:8(2022), pp. 3442-3448. [10.1021/jacs.1c11466]

Unveiling the Cation Exchange Reaction between the NASICON Li1.5Al0.5Ge1.5(PO4)3Solid Electrolyte and the pyr13TFSI Ionic Liquid

Paolella A.
Conceptualization
;
2022

Abstract

Recently, the formation of the ceramic-ionic liquid composite has attracted huge interest in the scientific community. In this work, we investigated the chemical reactions occurring between NASICON LAGP ceramic electrolyte and ionic liquid pyr13TFSI. This study allowed us to identify the cation exchange reaction pyr13-Li occurring on the LAGP surface, forming a LiTFSI salt that was detected by the nuclear magnetic resonance analysis. In addition, using 6Li foils, we succeeded in demonstrating that both LAGP and LiTFSI:pyr13TFSI participate in the diffusion of Li ions by the formation of an ionic bridge between two species.
2022
144
8
3442
3448
Unveiling the Cation Exchange Reaction between the NASICON Li1.5Al0.5Ge1.5(PO4)3Solid Electrolyte and the pyr13TFSI Ionic Liquid / Paolella, A.; Bertoni, G.; Zhu, W.; Campanella, D.; La Monaca, A.; Girard, G.; Demers, H.; Gheorghe Nita, A. C.; Feng, Z.; Vijh, A.; Guerfi, A.; Trudeau, M.; Armand, M.; Krachkovskiy, S. A.. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 144:8(2022), pp. 3442-3448. [10.1021/jacs.1c11466]
Paolella, A.; Bertoni, G.; Zhu, W.; Campanella, D.; La Monaca, A.; Girard, G.; Demers, H.; Gheorghe Nita, A. C.; Feng, Z.; Vijh, A.; Guerfi, A.; Trude...espandi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/1328526
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