Self-assembling minimalistic peptides embedded with an organocatalytic moiety were designed. By controlling the formation of fibrils via external intervention, it was shown that the activation is accelerated when the organocatalyst is in its supramolecular state. The effect of the accelerated catalysis was demonstrated in a Michael benchmark reaction.
Asymmetric Organocatalysis Accelerated via Self-Assembled Minimal Structures / Sinibaldi, A.; Della Penna, F.; Ponzetti, M.; Fini, F.; Marchesan, S.; Baschieri, A.; Pesciaioli, F.; Carlone, A.. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2021:39(2021), pp. 5403-5406. [10.1002/ejoc.202101042]
Asymmetric Organocatalysis Accelerated via Self-Assembled Minimal Structures
Fini F.;
2021
Abstract
Self-assembling minimalistic peptides embedded with an organocatalytic moiety were designed. By controlling the formation of fibrils via external intervention, it was shown that the activation is accelerated when the organocatalyst is in its supramolecular state. The effect of the accelerated catalysis was demonstrated in a Michael benchmark reaction.
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European J Organic Chem - 2021 - Sinibaldi - Asymmetric Organocatalysis Accelerated via Self Assembled Minimal Structures.pdf
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