Applying magnetic substrates, magnetized perpendicular to the surface, we were able to crystallize from racemic solution pure conglomerates of several molecules. The resolution is based on the spin-dependent charge reorganization (SDCR) effect. By having two surfaces with opposite magnetization, it was possible to simultaneously crystallize on each surface a different enantiomer. The method does not require any seeding or chemical modification and is generally employable to any conglomerate. A system is presented for performing the separation, while the racemic mixture flows between the two magnetic surfaces.

Simultaneous High-Purity Enantiomeric Resolution of Conglomerates Using Magnetic Substrates / Bhowmick, D.; Sang, Y.; Santra, K.; Halbauer, M.; Capua, E.; Paltiel, Y.; Naaman, R.; Tassinari, F.. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 21:5(2021), pp. 2925-2931. [10.1021/acs.cgd.1c00093]

Simultaneous High-Purity Enantiomeric Resolution of Conglomerates Using Magnetic Substrates

Naaman R.;Tassinari F.
2021

Abstract

Applying magnetic substrates, magnetized perpendicular to the surface, we were able to crystallize from racemic solution pure conglomerates of several molecules. The resolution is based on the spin-dependent charge reorganization (SDCR) effect. By having two surfaces with opposite magnetization, it was possible to simultaneously crystallize on each surface a different enantiomer. The method does not require any seeding or chemical modification and is generally employable to any conglomerate. A system is presented for performing the separation, while the racemic mixture flows between the two magnetic surfaces.
2021
21
5
2925
2931
Simultaneous High-Purity Enantiomeric Resolution of Conglomerates Using Magnetic Substrates / Bhowmick, D.; Sang, Y.; Santra, K.; Halbauer, M.; Capua, E.; Paltiel, Y.; Naaman, R.; Tassinari, F.. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 21:5(2021), pp. 2925-2931. [10.1021/acs.cgd.1c00093]
Bhowmick, D.; Sang, Y.; Santra, K.; Halbauer, M.; Capua, E.; Paltiel, Y.; Naaman, R.; Tassinari, F.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/1261981
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