The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.

Spin-Dependent Enantioselective Electropolymerization / Tassinari, F.; Amsallem, D.; Bloom, B. P.; Lu, Y.; Bedi, A.; Waldeck, D. H.; Gidron, O.; Naaman, R.. - In: JOURNAL OF PHYSICAL CHEMISTRY. C. - ISSN 1932-7447. - 124:38(2020), pp. 20974-20980. [10.1021/acs.jpcc.0c06238]

Spin-Dependent Enantioselective Electropolymerization

Tassinari F.
;
Naaman R.
2020

Abstract

The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.
2020
124
38
20974
20980
Spin-Dependent Enantioselective Electropolymerization / Tassinari, F.; Amsallem, D.; Bloom, B. P.; Lu, Y.; Bedi, A.; Waldeck, D. H.; Gidron, O.; Naaman, R.. - In: JOURNAL OF PHYSICAL CHEMISTRY. C. - ISSN 1932-7447. - 124:38(2020), pp. 20974-20980. [10.1021/acs.jpcc.0c06238]
Tassinari, F.; Amsallem, D.; Bloom, B. P.; Lu, Y.; Bedi, A.; Waldeck, D. H.; Gidron, O.; Naaman, R.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/1260525
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