The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.
Spin-Dependent Enantioselective Electropolymerization / Tassinari, F.; Amsallem, D.; Bloom, B. P.; Lu, Y.; Bedi, A.; Waldeck, D. H.; Gidron, O.; Naaman, R.. - In: JOURNAL OF PHYSICAL CHEMISTRY. C. - ISSN 1932-7447. - 124:38(2020), pp. 20974-20980. [10.1021/acs.jpcc.0c06238]
Spin-Dependent Enantioselective Electropolymerization
Tassinari F.
;Naaman R.
2020
Abstract
The electro-oxidative polymerization of an enantiopure chiral 3,4-ethylenedioxythiophene monomer, performed using spin-polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the chiral-induced spin selectivity effect.
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