Reaction of dienes, e.g. H2C:CH(CH2)nCH:CH2 (n = 2-4), Me2C:CHCH2CH2CMe:CHCH2OAc, 1,5- and 1,4-cyclooctadiene, and 4-vinylcyclohexenes, with the title reagents resulted in chlorination of the more highly substituted double bond.
DIENE CHLORINATION WITH MANGANESE-DIOXIDE TRIMETHYL-CHLOROSILANE / Bellesia, Franco; Ghelfi, Franco; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: JOURNAL OF CHEMICAL RESEARCH. SYNOPSES. - ISSN 0308-2342. - STAMPA. - -:(1989), pp. 360-361.
DIENE CHLORINATION WITH MANGANESE-DIOXIDE TRIMETHYL-CHLOROSILANE
BELLESIA, Franco;GHELFI, Franco;PAGNONI, Ugo Maria;PINETTI, Adriano
1989
Abstract
Reaction of dienes, e.g. H2C:CH(CH2)nCH:CH2 (n = 2-4), Me2C:CHCH2CH2CMe:CHCH2OAc, 1,5- and 1,4-cyclooctadiene, and 4-vinylcyclohexenes, with the title reagents resulted in chlorination of the more highly substituted double bond.
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