Dissociation and stability constants for protolytic and complex formation equilibria of a polyfunctional ligand are determined. Deprotonation is monitored by NMR controlled titrations. Macroscopic and microscopic concepts are discussed. Nickel complexes are more stable than those of Ca and Mg.
Pyridin-2-YL-(I-propylamino)-methane phosphonic acid - Protonation and metal complex formation - NMR-controlled titration / Bier, A.; Failla, S.; Finocchiaro, P.; Hagele, G.; Latronico, M.; Libertini, E.; Ollig, J.. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - 155:1(1999), pp. 89-100. [10.1080/10426509908044973]
Pyridin-2-YL-(I-propylamino)-methane phosphonic acid - Protonation and metal complex formation - NMR-controlled titration
Libertini E.;
1999
Abstract
Dissociation and stability constants for protolytic and complex formation equilibria of a polyfunctional ligand are determined. Deprotonation is monitored by NMR controlled titrations. Macroscopic and microscopic concepts are discussed. Nickel complexes are more stable than those of Ca and Mg.
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