Manganese(III) acetate-acetyl chloride smoothly halogenates benzenes at the aromatic nucleus while benzylic chlorination is observed on substrates bearing an electron-donor substituent and an ortho or para methyl group; the results are rationalized by a reaction pathway involving a single electron transfer from the substrate to a manganese(III) species.
REACTION OF MANGANESE(III) ACETATE-ACETYL CHLORIDE WITH BENZENES / Bellesia, Franco; Ghelfi, Franco; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: JOURNAL OF CHEMICAL RESEARCH. SYNOPSES. - ISSN 0308-2342. - STAMPA. - -:(1991), pp. 284-285.
REACTION OF MANGANESE(III) ACETATE-ACETYL CHLORIDE WITH BENZENES
BELLESIA, Franco;GHELFI, Franco;PAGNONI, Ugo Maria;PINETTI, Adriano
1991
Abstract
Manganese(III) acetate-acetyl chloride smoothly halogenates benzenes at the aromatic nucleus while benzylic chlorination is observed on substrates bearing an electron-donor substituent and an ortho or para methyl group; the results are rationalized by a reaction pathway involving a single electron transfer from the substrate to a manganese(III) species.
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