The chlorotrimethylsilane-dimethyl sulphoxide reagent system gives rise to smooth and high yield transformations of: i) beta-alkyl- and beta,beta-dialkyl-styrenes into vicinal dichlorides, ii) alpha,beta-dialkyl- and alpha,beta,beta-trialkyl-styrenes into allyl chlorides.
THE REACTION OF STYRENES WITH CHLOROTRIMETHYLSILANE DIMETHYL-SULFOXIDE / Bellesia, Franco; Ghelfi, Franco; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - STAMPA. - 121:(1991), pp. 559-561.
THE REACTION OF STYRENES WITH CHLOROTRIMETHYLSILANE DIMETHYL-SULFOXIDE
BELLESIA, Franco;GHELFI, Franco;PAGNONI, Ugo Maria;PINETTI, Adriano
1991
Abstract
The chlorotrimethylsilane-dimethyl sulphoxide reagent system gives rise to smooth and high yield transformations of: i) beta-alkyl- and beta,beta-dialkyl-styrenes into vicinal dichlorides, ii) alpha,beta-dialkyl- and alpha,beta,beta-trialkyl-styrenes into allyl chlorides.
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