A stable hybrid material (Mt-Fe(III)Phen) formed by intercalation of the μ-oxo Fe(III)-phenanthroline complex [(OH2)3(Phen)FeOFe(Phen)(OH2)3]4+ (Fe(III)Phen) in montmorillonite (Mt) is able to immobilize H2S in gaseous phase with high efficiency even at extremely low pressures. DR UV–vis and I.R. spectroscopies, elemental analysis, X-ray powder diffraction, thermal analysis coupled with evolved gas mass spectrometry, and X-ray absorption spectroscopy show that the material has high adsorption capacity, performs fast H2S trapping and is long-lasting. Moreover, even extremely low levels of H2S can be removed easily and quickly from gaseous phase using a suitable amount of the trapping material. The immobilization mechanism likely involves a redox reaction between iron (III) and one S2− ion, followed by the binding of a second S2− ion to the metal centre. The process takes place at room temperature, is reversible for several cycles, and does not require pre-treatment of neither gaseous H2S nor the adsorbent material. Therefore, this modified montmorillonite is a promising material to get rid of H2S in processes of environmental interest and to obtain gaseous (and gasifiable) high quality hydrocarbons in fuels refineries.
Chemical trapping of gaseous H2S at high and low partial pressures by an iron complex immobilized inside the montmorillonite interlayer / Malferrari, Daniele; Castellini, Elena; Bernini, Fabrizio; Serrano Rubio, Aida; Rafael Castro, German; Ignacio Sainz-Díaz, Claro; Caleffi, Matteo; Brigatti, Maria Franca; Borsari, Marco. - In: MICROPOROUS AND MESOPOROUS MATERIALS. - ISSN 1387-1811. - 265:(2018), pp. 8-17. [10.1016/j.micromeso.2018.01.017]
Chemical trapping of gaseous H2S at high and low partial pressures by an iron complex immobilized inside the montmorillonite interlayer
Daniele Malferrari;Elena Castellini
;Fabrizio Bernini;Maria Franca Brigatti;Marco Borsari
2018
Abstract
A stable hybrid material (Mt-Fe(III)Phen) formed by intercalation of the μ-oxo Fe(III)-phenanthroline complex [(OH2)3(Phen)FeOFe(Phen)(OH2)3]4+ (Fe(III)Phen) in montmorillonite (Mt) is able to immobilize H2S in gaseous phase with high efficiency even at extremely low pressures. DR UV–vis and I.R. spectroscopies, elemental analysis, X-ray powder diffraction, thermal analysis coupled with evolved gas mass spectrometry, and X-ray absorption spectroscopy show that the material has high adsorption capacity, performs fast H2S trapping and is long-lasting. Moreover, even extremely low levels of H2S can be removed easily and quickly from gaseous phase using a suitable amount of the trapping material. The immobilization mechanism likely involves a redox reaction between iron (III) and one S2− ion, followed by the binding of a second S2− ion to the metal centre. The process takes place at room temperature, is reversible for several cycles, and does not require pre-treatment of neither gaseous H2S nor the adsorbent material. Therefore, this modified montmorillonite is a promising material to get rid of H2S in processes of environmental interest and to obtain gaseous (and gasifiable) high quality hydrocarbons in fuels refineries.File | Dimensione | Formato | |
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