Solutions of very low concentrations cannot be treated by the usual concept of concentration. Stochastic calculations are performed for the analysis of such solutions containing one or a few molecule(s). It is concluded that these systems escape the usual concentration parameters. Two “case histories” are also shown for demonstration of the practical consequences of the theoretical analysis.

Limits of the Classical Concept of Concentration / Maioli, Marco; Varadi, Gyula; Kurdi, Róbert; Caglioti, Luciano; Palyi, Gyula. - In: THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS. - ISSN 1948-7185. - STAMPA. - 120:(2016), pp. 7438-7445. [10.1021/acs.jpcb.6b02904]

Limits of the Classical Concept of Concentration

MAIOLI, Marco;PALYI, Gyula
2016

Abstract

Solutions of very low concentrations cannot be treated by the usual concept of concentration. Stochastic calculations are performed for the analysis of such solutions containing one or a few molecule(s). It is concluded that these systems escape the usual concentration parameters. Two “case histories” are also shown for demonstration of the practical consequences of the theoretical analysis.
2016
20-lug-2016
120
7438
7445
Limits of the Classical Concept of Concentration / Maioli, Marco; Varadi, Gyula; Kurdi, Róbert; Caglioti, Luciano; Palyi, Gyula. - In: THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS. - ISSN 1948-7185. - STAMPA. - 120:(2016), pp. 7438-7445. [10.1021/acs.jpcb.6b02904]
Maioli, Marco; Varadi, Gyula; Kurdi, Róbert; Caglioti, Luciano; Palyi, Gyula
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/1145088
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