Solutions of very low concentrations cannot be treated by the usual concept of concentration. Stochastic calculations are performed for the analysis of such solutions containing one or a few molecule(s). It is concluded that these systems escape the usual concentration parameters. Two “case histories” are also shown for demonstration of the practical consequences of the theoretical analysis.
Limits of the Classical Concept of Concentration / Maioli, Marco; Varadi, Gyula; Kurdi, Róbert; Caglioti, Luciano; Palyi, Gyula. - In: THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS. - ISSN 1948-7185. - STAMPA. - 120:30(2016), pp. 7438-7445. [10.1021/acs.jpcb.6b02904]
Limits of the Classical Concept of Concentration
MAIOLI, Marco;PALYI, Gyula
2016
Abstract
Solutions of very low concentrations cannot be treated by the usual concept of concentration. Stochastic calculations are performed for the analysis of such solutions containing one or a few molecule(s). It is concluded that these systems escape the usual concentration parameters. Two “case histories” are also shown for demonstration of the practical consequences of the theoretical analysis.
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