Various types of polyfunctionalised stereodefined organic molecules appear to be highly serviceable as organocatalysts in the asymmetric synthesis of nitrogen-containing compounds. Beyond name reactions such as the aza-Henry, the Friedel-Crafts, and the Strecker other representative transformations like the hydrophosphonylation can be easily approached by using the suitable organocatalytic species and are herein reported with a special emphasis placed on the reaction and stereochemical outcomes and on the mechanistic insights.
Organocatalysis in the Asymmetric Synthesis of Nitrogen-Containing Compounds: How and Why / Bernardi, Luca; Fini, Francesco; Fochi, Mariafrancesca; Ricci, Alfredo. - In: CHIMIA. - ISSN 0009-4293. - STAMPA. - 61:(2007), pp. 224-231. [10.2533/chimia.2007.224]
Organocatalysis in the Asymmetric Synthesis of Nitrogen-Containing Compounds: How and Why
FINI, Francesco;
2007
Abstract
Various types of polyfunctionalised stereodefined organic molecules appear to be highly serviceable as organocatalysts in the asymmetric synthesis of nitrogen-containing compounds. Beyond name reactions such as the aza-Henry, the Friedel-Crafts, and the Strecker other representative transformations like the hydrophosphonylation can be easily approached by using the suitable organocatalytic species and are herein reported with a special emphasis placed on the reaction and stereochemical outcomes and on the mechanistic insights.File | Dimensione | Formato | |
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