The crystal and molecular structure of the [N(2-ammoniumethyl)piperazinium]tetrachloromonobromocuprate(II) monohydrate is reported. The crystals are monoclinic, space group P2(1)/c, Z = 4, with a = 9.560(2), b = 9.240(3), c = 18.270(7) angstrom, beta = 99.20(2)degrees. The structure consists of discrete N(2-ammoniumethyl)piperazinium cations, uncoordinated water molecules and [CuCl4Br]3- anions, in which four coplanar chlorine atoms occupy the square-basal plane and one bromine atom the axial position, giving the copper(II) ion a moderately elongated square-pyramidal geometry. The structure was refined to a final R index of 0.0765.

[N(2-AMMONIUMETHYL)PIPERAZINIUM]TETRACHLOROMONOBROMOCUPRATE(II) MONOHYDRATE - A COMPOUND CONTAINING A DISCRETE SQUARE-PYRAMIDAL UNIT / Battaglia, Lp; Corradi, Anna; Ianelli, S.. - In: JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH. - ISSN 0277-8068. - STAMPA. - 23:(1993), pp. 411-415.

[N(2-AMMONIUMETHYL)PIPERAZINIUM]TETRACHLOROMONOBROMOCUPRATE(II) MONOHYDRATE - A COMPOUND CONTAINING A DISCRETE SQUARE-PYRAMIDAL UNIT

CORRADI, Anna;
1993

Abstract

The crystal and molecular structure of the [N(2-ammoniumethyl)piperazinium]tetrachloromonobromocuprate(II) monohydrate is reported. The crystals are monoclinic, space group P2(1)/c, Z = 4, with a = 9.560(2), b = 9.240(3), c = 18.270(7) angstrom, beta = 99.20(2)degrees. The structure consists of discrete N(2-ammoniumethyl)piperazinium cations, uncoordinated water molecules and [CuCl4Br]3- anions, in which four coplanar chlorine atoms occupy the square-basal plane and one bromine atom the axial position, giving the copper(II) ion a moderately elongated square-pyramidal geometry. The structure was refined to a final R index of 0.0765.
1993
23
411
415
[N(2-AMMONIUMETHYL)PIPERAZINIUM]TETRACHLOROMONOBROMOCUPRATE(II) MONOHYDRATE - A COMPOUND CONTAINING A DISCRETE SQUARE-PYRAMIDAL UNIT / Battaglia, Lp; Corradi, Anna; Ianelli, S.. - In: JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH. - ISSN 0277-8068. - STAMPA. - 23:(1993), pp. 411-415.
Battaglia, Lp; Corradi, Anna; Ianelli, S.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/11154
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 1
  • ???jsp.display-item.citation.isi??? 1
social impact