A polymer supported palladium catalyst, obtained by copolymerization of Pd(AAEMA)<inf>2</inf> [AAEMA<sup>-</sup> = deprotonated form of 2-(acetoacetoxy) ethyl methacrylate] with ethyl methacrylate (co-monomer) and ethylene glycol dimethacrylate (cross-linker), exhibited excellent activity and selectivity for the hydrogenation of quinolines to 1,2,3,4-tetrahydroquinolines in the presence of NaBH<inf>4</inf> as hydrogen donor in water. Both the activity and selectivity could be maintained for at least seven reaction runs. No metal leaching into solution occurred during recycles. TEM analyzes carried out on the catalyst showed that the active species were supported palladium nanoparticles having a mean size of 3 nm, which did not aggregate with the recycles.

A polymer supported palladium(II) β-ketoesterate complex as active and recyclable pre-catalyst for selective reduction of quinolines in water with sodium borohydride / Dell'Anna, M.M., Romanazzi, G., Intini, S., Rizzuti, A., Leonelli, C., Piccinni, A.F., Mastrorilli, P.. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - ELETTRONICO. - 402:(2015), pp. 83-91. [10.1016/j.molcata.2015.03.013]

A polymer supported palladium(II) β-ketoesterate complex as active and recyclable pre-catalyst for selective reduction of quinolines in water with sodium borohydride

RIZZUTI, Antonino;LEONELLI, Cristina;
2015

Abstract

A polymer supported palladium catalyst, obtained by copolymerization of Pd(AAEMA)2 [AAEMA- = deprotonated form of 2-(acetoacetoxy) ethyl methacrylate] with ethyl methacrylate (co-monomer) and ethylene glycol dimethacrylate (cross-linker), exhibited excellent activity and selectivity for the hydrogenation of quinolines to 1,2,3,4-tetrahydroquinolines in the presence of NaBH4 as hydrogen donor in water. Both the activity and selectivity could be maintained for at least seven reaction runs. No metal leaching into solution occurred during recycles. TEM analyzes carried out on the catalyst showed that the active species were supported palladium nanoparticles having a mean size of 3 nm, which did not aggregate with the recycles.
2015
no
Inglese
AMSTERDAM
402
83
91
WOS:000353600500012
2-s2.0-84925695617
http://www.sciencedirect.com.scopeesprx.elsevier.com/science/article/pii/S138111691500117X
Pd nanoparticles; Polymer supported; Quinoline transfer hydrogenation; Recyclable catalyst; Water solvent; Catalysis; Physical and Theoretical Chemistry; Process Chemistry and Technology
The paper represents a fruitful collaboration between the UNIMORE and POLIBA. The two research groups have been collaborating on the morphological and chemical characterization of catalysts for organic synthesis for over then 25 years. This particular papers reports on catalytic reactions under extremely reducing conditions which could compromise the surface morphology on the catalyst.
partially_open
info:eu-repo/semantics/article
Contributo su RIVISTA::Articolo su rivista
262
A polymer supported palladium(II) β-ketoesterate complex as active and recyclable pre-catalyst for selective reduction of quinolines in water with sodium borohydride / Dell'Anna, M.M., Romanazzi, G., Intini, S., Rizzuti, A., Leonelli, C., Piccinni, A.F., Mastrorilli, P.. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - ELETTRONICO. - 402:(2015), pp. 83-91. [10.1016/j.molcata.2015.03.013]
Dell'Anna, Maria Michela; Romanazzi, Giuseppe; Intini, Simona; Rizzuti, Antonino; Leonelli, Cristina; Piccinni, Alberto Ferruccio; Mastrorilli, Piero...espandi
7
File in questo prodotto:
File Dimensione Formato  
Journal of Molecular Catalysis A Chemical 402 2015 83–91.pdf

Accesso riservato

Descrizione: Articolo pubblicato
Tipologia: VOR - Versione pubblicata dall'editore
Dimensione 2.43 MB
Formato Adobe PDF
  Visualizza/Apri   Richiedi una copia
2.43 MB Adobe PDF   Visualizza/Apri   Richiedi una copia
1106449.pdf

Open access

Tipologia: AAM - Versione dell'autore revisionata e accettata per la pubblicazione
Dimensione 456.25 kB
Formato Adobe PDF
Visualizza/Apri
456.25 kB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

Licenza Creative Commons
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/1106449
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 25
  • ???jsp.display-item.citation.isi??? 25
social impact