2-Chloro acid methyl esters were prepared in good yields treating 2-chloro aldehyde dimethyl acetals with trichloroisocyanuric acid in DMF. Aldehyde dimethyl acetals with the 2-halogen on a tertiary carbon atom were poorly reactive and could be oxidized effeciently only after their transformation into 1,3-dioxolanes.
TRICHLOROISOCYANURIC ACID OXIDATION OF 2-CHLORO ALDEHYDE ACETALS TO 2-CHLORO ACID-ESTERS / Boni, M; Ghelfi, Franco; Pagnoni, Ugo Maria; Pinetti, Adriano. - In: BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN. - ISSN 0009-2673. - STAMPA. - 67:(1994), pp. 156-159.
TRICHLOROISOCYANURIC ACID OXIDATION OF 2-CHLORO ALDEHYDE ACETALS TO 2-CHLORO ACID-ESTERS
GHELFI, Franco;PAGNONI, Ugo Maria;PINETTI, Adriano
1994
Abstract
2-Chloro acid methyl esters were prepared in good yields treating 2-chloro aldehyde dimethyl acetals with trichloroisocyanuric acid in DMF. Aldehyde dimethyl acetals with the 2-halogen on a tertiary carbon atom were poorly reactive and could be oxidized effeciently only after their transformation into 1,3-dioxolanes.
Pubblicazioni consigliate
I metadati presenti in IRIS UNIMORE sono rilasciati con licenza Creative Commons CC0 1.0 Universal, mentre i file delle pubblicazioni sono rilasciati con licenza Attribuzione 4.0 Internazionale (CC BY 4.0), salvo diversa indicazione.
In caso di violazione di copyright, contattare Supporto Iris
