Compound [Cr5(tpda)4Cl2] (H2tpda = N2,N6-di(pyridin-2-yl)pyridine-2,6-diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.
Magnetic Blocking in Extended Metal Atom Chains: a Pentachromium(II) Complex Behaving as a Single-molecule Magnet / Cornia, Andrea; Rigamonti, Luca; Simone, Boccedi; Rodolphe, Clérac; Mathieu, Rouzières; Lorenzo, Sorace. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 50:96(2014), pp. 15191-15194. [10.1039/c4cc06693f]
Magnetic Blocking in Extended Metal Atom Chains: a Pentachromium(II) Complex Behaving as a Single-molecule Magnet
CORNIA, Andrea;RIGAMONTI, Luca;
2014
Abstract
Compound [Cr5(tpda)4Cl2] (H2tpda = N2,N6-di(pyridin-2-yl)pyridine-2,6-diamine), an Extended Metal Atom Chain complex featuring two quadruply-bonded {Cr2} units, exhibits field-induced slow relaxation of its magnetization arising from the terminal chromium(II) ion and provides the first example of a chromium(II)-based Single-Molecule Magnet.
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