A wide series of empirical parameters of solvents are employed in the study of the dependence of the redox potentials of some dirhodium(II) derivatives [namely, Rh2(O2CCF3)2(form)2, Rh2(form)4, Rh2(ONHCF3)4] upon the solvent nature. A statistical approach is proposed which analyzes the influence of solvent basicity, acidity and polarizability both independently and jointly. This has proved to be useful in rationalizing the solvent effects on the redox potentials, as well as in suggesting different solvation models.
The standard redox potential in the study of solute—solvent interactions. Dirhodium complexes / Seeber, Renato; Paola, Piu; Pasquale, Piraino; Piero, Zanello. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 155:(1989), pp. 27-30. [10.1016/S0020-1693(00)89277-4]
The standard redox potential in the study of solute—solvent interactions. Dirhodium complexes
SEEBER, Renato;
1989
Abstract
A wide series of empirical parameters of solvents are employed in the study of the dependence of the redox potentials of some dirhodium(II) derivatives [namely, Rh2(O2CCF3)2(form)2, Rh2(form)4, Rh2(ONHCF3)4] upon the solvent nature. A statistical approach is proposed which analyzes the influence of solvent basicity, acidity and polarizability both independently and jointly. This has proved to be useful in rationalizing the solvent effects on the redox potentials, as well as in suggesting different solvation models.
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