Intramolecular participation of carbon-carbon double bonds and hydroxy-groups can occur when alcohols are treted with complexes derived from dimethyl sulphide and N-halogenosuccinimide. Neighbouring group participation is more common in the reactions in which N-bromosuccinimide rather than N-chlorosuccinimide is employed, the results suggest caution when the alcohol to halide conversion is attempted in certain polyfunctional molecules.

Some Anomalous Products from the Attempted Halogenation of Unsaturated Alcohols by the Complex from Dimethyl Sulphide and N-Halogenosuccinimide / Bellesia, Franco; R., Grandi; Pagnoni, Ugo Maria; R., Trave. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - STAMPA. - 1:(1979), pp. 851-855.

Some Anomalous Products from the Attempted Halogenation of Unsaturated Alcohols by the Complex from Dimethyl Sulphide and N-Halogenosuccinimide

BELLESIA, Franco;PAGNONI, Ugo Maria;
1979

Abstract

Intramolecular participation of carbon-carbon double bonds and hydroxy-groups can occur when alcohols are treted with complexes derived from dimethyl sulphide and N-halogenosuccinimide. Neighbouring group participation is more common in the reactions in which N-bromosuccinimide rather than N-chlorosuccinimide is employed, the results suggest caution when the alcohol to halide conversion is attempted in certain polyfunctional molecules.
1979
1
851
855
Some Anomalous Products from the Attempted Halogenation of Unsaturated Alcohols by the Complex from Dimethyl Sulphide and N-Halogenosuccinimide / Bellesia, Franco; R., Grandi; Pagnoni, Ugo Maria; R., Trave. - In: JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I. - ISSN 0300-922X. - STAMPA. - 1:(1979), pp. 851-855.
Bellesia, Franco; R., Grandi; Pagnoni, Ugo Maria; R., Trave
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/646098
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