The dinuclear oxo!rhenium"V#\ m!OReO"Me1pymS#11 species was prepared by the reaction of 3\5!dimethylpyrimidine!1"0H#!thione "Me1pymSH# with trans!ReI1"EtO# "PPh2#1 or trans!ReO1py3Cl=1H1O in di}erent solvents[ The compounds were char!acterized by elemental analysis\ magnetic susceptibility\ UV!VIS\ IR and 0H NMR spectroscopy and conductivity measurements[Cyclic voltammetry shows that the m!OReO"Me1pymS#11 species\ undergo a quasi!reversible single!electron process in which theoxygen!bridged dimeric framework is maintained[ The structure of m!OReO"Me1pymS#11 was determined by single!crystal X!raydi}raction methods[ The dinuclear structure of Re1O2"Me1pymS#3 compound consists of two ReO"Me1pymS#1 moieties bridgedby an oxygen atom[ The backbone O1ReORe1O is almost linear and each rhenium"V# ion lies in the center of a distortedoctahedron achieved through two deprotonated N\S!chelate ligands in the equatorial plane[ 0888 Elsevier Science Ltd[ All rightsreserved[

Synthesis, Crystal and Molecular Structure, Spectroscopic and Electrochemical Studies of -oxo-bis{oxo-bis(4,6-dimethylpyrimidine-2-thiolate)rhenium(V)} Complex / Battistuzzi, Gianantonio; Corradi, Anna; D., Dallari; Saladini, Monica; Battistuzzi, Raffaele. - In: POLYHEDRON. - ISSN 0277-5387. - STAMPA. - 18:(1998), pp. 57-63.

Synthesis, Crystal and Molecular Structure, Spectroscopic and Electrochemical Studies of -oxo-bis{oxo-bis(4,6-dimethylpyrimidine-2-thiolate)rhenium(V)} Complex

BATTISTUZZI, Gianantonio;CORRADI, Anna;SALADINI, Monica;BATTISTUZZI, Raffaele
1998

Abstract

The dinuclear oxo!rhenium"V#\ m!OReO"Me1pymS#11 species was prepared by the reaction of 3\5!dimethylpyrimidine!1"0H#!thione "Me1pymSH# with trans!ReI1"EtO# "PPh2#1 or trans!ReO1py3Cl=1H1O in di}erent solvents[ The compounds were char!acterized by elemental analysis\ magnetic susceptibility\ UV!VIS\ IR and 0H NMR spectroscopy and conductivity measurements[Cyclic voltammetry shows that the m!OReO"Me1pymS#11 species\ undergo a quasi!reversible single!electron process in which theoxygen!bridged dimeric framework is maintained[ The structure of m!OReO"Me1pymS#11 was determined by single!crystal X!raydi}raction methods[ The dinuclear structure of Re1O2"Me1pymS#3 compound consists of two ReO"Me1pymS#1 moieties bridgedby an oxygen atom[ The backbone O1ReORe1O is almost linear and each rhenium"V# ion lies in the center of a distortedoctahedron achieved through two deprotonated N\S!chelate ligands in the equatorial plane[ 0888 Elsevier Science Ltd[ All rightsreserved[
1998
18
57
63
Synthesis, Crystal and Molecular Structure, Spectroscopic and Electrochemical Studies of -oxo-bis{oxo-bis(4,6-dimethylpyrimidine-2-thiolate)rhenium(V)} Complex / Battistuzzi, Gianantonio; Corradi, Anna; D., Dallari; Saladini, Monica; Battistuzzi, Raffaele. - In: POLYHEDRON. - ISSN 0277-5387. - STAMPA. - 18:(1998), pp. 57-63.
Battistuzzi, Gianantonio; Corradi, Anna; D., Dallari; Saladini, Monica; Battistuzzi, Raffaele
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11380/592105
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