Fluorine-containing beta-diketones were reduced by free baker's yeast and immobilized baker's yeast in water to give optically active fluorinated beta-hydroxyketones. It was found that the reaction is higly regioselective and that the stereochemistry of the reduction is controlled by the R substituent.
Substituent Effect on the Absolute Stereochemistry of the Asymmetric Reduction of Fluorine-Containing beta-Diketones by Bakers' Yeast / Bucciarelli, Maria; Forni, Arrigo; Moretti, Irene; Prati, Fabio; Torre, Giovanni. - In: BIOCATALYSIS. - ISSN 0886-4454. - STAMPA. - 9:(1994), pp. 313-313.
Substituent Effect on the Absolute Stereochemistry of the Asymmetric Reduction of Fluorine-Containing beta-Diketones by Bakers' Yeast.
BUCCIARELLI, Maria;FORNI, Arrigo;MORETTI, Irene;PRATI, Fabio;TORRE, Giovanni
1994
Abstract
Fluorine-containing beta-diketones were reduced by free baker's yeast and immobilized baker's yeast in water to give optically active fluorinated beta-hydroxyketones. It was found that the reaction is higly regioselective and that the stereochemistry of the reduction is controlled by the R substituent.
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