The crystal structures of neutral cis- and trans-[Pt(dimethylsulfoxide)(thiazole)Cl2] have been determined by X-ray diffraction. The longer C4-C5 bond distance of the N-coordinated thiazole in both the square planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orbital system of the thiazolic ring.
The bonding of thiazoles to platinum(II) complexes. X-ray crystal structure of cis- and trans-[Pt(dimethyl sulfoxide)(thiazole)Cl-2] / Cornia, Andrea; FABRETTI COSTANTINO, Antonio; M., Bonivento; L., Cattalini. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 255:(1997), pp. 405-409.
The bonding of thiazoles to platinum(II) complexes. X-ray crystal structure of cis- and trans-[Pt(dimethyl sulfoxide)(thiazole)Cl-2]
CORNIA, Andrea;FABRETTI COSTANTINO, Antonio;
1997
Abstract
The crystal structures of neutral cis- and trans-[Pt(dimethylsulfoxide)(thiazole)Cl2] have been determined by X-ray diffraction. The longer C4-C5 bond distance of the N-coordinated thiazole in both the square planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orbital system of the thiazolic ring.
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