The title compound consists of [ReO(NCS)(2)(OEt)(PPh3)(2)] units in which the rhenium(V) center shows a slightly distorted octahedral coordination. The two N-coordinated NCS- groups are trans to each other, as the Re=O and the Re-Oft units. The Re=O and Re-OEt bond lengths [1.682(10) and 1.871(10) Angstrom, respectively] and the geometry about the ethoxide oxygen atom indicate that in both cases M-O ligation has a considerable degree of multiple bond. (C) 2000 Elsevier Science S.A. All rights reserved.
Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex / Battistuzzi, Raffaele; Saladini, Monica. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 304:1(2000), pp. 114-117. [10.1016/S0020-1693(00)00057-8]
Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex
BATTISTUZZI, Raffaele;SALADINI, Monica
2000
Abstract
The title compound consists of [ReO(NCS)(2)(OEt)(PPh3)(2)] units in which the rhenium(V) center shows a slightly distorted octahedral coordination. The two N-coordinated NCS- groups are trans to each other, as the Re=O and the Re-Oft units. The Re=O and Re-OEt bond lengths [1.682(10) and 1.871(10) Angstrom, respectively] and the geometry about the ethoxide oxygen atom indicate that in both cases M-O ligation has a considerable degree of multiple bond. (C) 2000 Elsevier Science S.A. All rights reserved.
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