Reaction of sterically congested aromatic ketones with the McMurry reagent (4TiCl3,LiAlH4) in tetrahydrofuran yields is not only the olefins (E- and Z-isomers), but also the corresponding ethanes and some other products. We have studied the minor or non-normal products of this reaction.
Reductive coupling of aromatic ketones by low-valent titanium salts / Bottino, F. A.; Finocchiaro, P.; Libertini, E.; Reale, A.; Recca, A.. - In: JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS II. - ISSN 0300-9238. - 1(1982), pp. 77-81. [10.1039/p29820000077]
Reductive coupling of aromatic ketones by low-valent titanium salts
Libertini E.;
1982
Abstract
Reaction of sterically congested aromatic ketones with the McMurry reagent (4TiCl3,LiAlH4) in tetrahydrofuran yields is not only the olefins (E- and Z-isomers), but also the corresponding ethanes and some other products. We have studied the minor or non-normal products of this reaction.Pubblicazioni consigliate
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