The syntheses and characterization of new spirocyclophosphazenes is reported. Variable-temperature n.m.r. measurements strongly suggest the presence of only one isomer for our compounds. Only tris-(3-methoxyphenyl-1,2-dioxy) phosphonitrile trimer has been found to form clathrate compounds with cyclohexene, n-heptane, and 1,2-dichloroethane.
Syntheses, stereochemistry, and inclusion properties of new spirocyclophosphazenes / Finocchiaro, P.; Libertini, E.; Recca, A.. - In: JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS I. - ISSN 0300-9599. - 11(1984), pp. 1735-1736. [10.1039/p29840001735]
Syntheses, stereochemistry, and inclusion properties of new spirocyclophosphazenes
Libertini E.;
1984
Abstract
The syntheses and characterization of new spirocyclophosphazenes is reported. Variable-temperature n.m.r. measurements strongly suggest the presence of only one isomer for our compounds. Only tris-(3-methoxyphenyl-1,2-dioxy) phosphonitrile trimer has been found to form clathrate compounds with cyclohexene, n-heptane, and 1,2-dichloroethane.
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