O-Silylation of acylcobalt tetracarbonyls, RC(O)Co(CO)4, gives the dinuclear carbene complexes [{mu-2-RC(OSiR'3)}(mu-2-CO)Co2(CO)6], of which one derivative (R = Me, R' = Ph) was characterized by X-ray diffraction.
O-SILYLATION OF ACYLCOBALT TETRACARBONYLS - SYNTHESIS OF A NEW TYPE OF DINUCLEAR MU-2-HYDROXYCARBENE COBALT CARBONYL DERIVATIVES / Sisak, A; Sironi, A; Moret, M; Zucchi, Claudia; Ghelfi, Franco; Palyi, Gyula. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - -:(1991), pp. 176-178.
O-SILYLATION OF ACYLCOBALT TETRACARBONYLS - SYNTHESIS OF A NEW TYPE OF DINUCLEAR MU-2-HYDROXYCARBENE COBALT CARBONYL DERIVATIVES
ZUCCHI, Claudia;GHELFI, Franco;PALYI, Gyula
1991
Abstract
O-Silylation of acylcobalt tetracarbonyls, RC(O)Co(CO)4, gives the dinuclear carbene complexes [{mu-2-RC(OSiR'3)}(mu-2-CO)Co2(CO)6], of which one derivative (R = Me, R' = Ph) was characterized by X-ray diffraction.
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