Diels or no Diels? A bifunctional organic catalyst based on the thiourea motif is able to coordinate both diene and dienophile in an unprecedented asymmetric Diels–Alder reaction of 3-vinylindole derivatives, giving a rapid access to optically active tetra- and hexahydrocarbazoles with excellent results in terms of yields, diastereoselectivities, and enantioselectivities.
Organocatalytic Asymmetric Diels-Alder Reactions of 3-Vinylindoles / Gioia, Claudio; Hauville, Agnès; Bernardi, Luca; Fini, Francesco; Ricci, Alfredo. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 47:48(2008), pp. 9236-9239. [10.1002/anie.200804275]
Organocatalytic Asymmetric Diels-Alder Reactions of 3-Vinylindoles
FINI, Francesco;
2008
Abstract
Diels or no Diels? A bifunctional organic catalyst based on the thiourea motif is able to coordinate both diene and dienophile in an unprecedented asymmetric Diels–Alder reaction of 3-vinylindole derivatives, giving a rapid access to optically active tetra- and hexahydrocarbazoles with excellent results in terms of yields, diastereoselectivities, and enantioselectivities.File | Dimensione | Formato | |
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