In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.
Effective ruthenium-catalyzed oxidation of chlorinated olefins by monopersulfate in aqueous medium / M., Bressan; Forti, Luca; A., Morvillo. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - STAMPA. - 1994:(1994), pp. 253-254. [10.1039/c39940000253]
Effective ruthenium-catalyzed oxidation of chlorinated olefins by monopersulfate in aqueous medium
FORTI, Luca;
1994
Abstract
In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.
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