In the present work the behavior of different substituted iminic bonds toward the oxidative action of 3-chloroperbenzoic acid is reported. The C=N bond was or was not oxidized to oxaziridines, amides, oximes, nitroso-, nitro-, and azodioxy compounds depending on the substituents at the iminic group and on the imine/MCPBA stoichiometric ratio.
On the oxidation of different iminic bonds by excess of 3-chloroperbenzoic acid / Troisi, L.; Carrozzo, ; M., M.; Citti, Ca; Falcicchio, A; Mansueto, R; Rosato, F; Cannazza, Giuseppe. - In: SYNLETT. - ISSN 0936-5214. - STAMPA. - 24:(2013), pp. 53-56. [10.1055/s-0032-1317760]
On the oxidation of different iminic bonds by excess of 3-chloroperbenzoic acid
CANNAZZA, Giuseppe
2013
Abstract
In the present work the behavior of different substituted iminic bonds toward the oxidative action of 3-chloroperbenzoic acid is reported. The C=N bond was or was not oxidized to oxaziridines, amides, oximes, nitroso-, nitro-, and azodioxy compounds depending on the substituents at the iminic group and on the imine/MCPBA stoichiometric ratio.
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